You "could" add on to it and put a vent in the end of it but securing the addition might cause a weak area that would end up leaking over time. My dad also has an 02 Silverado but can't remember exactly what's going on under there because I've never really paid attention under the back seat of those trucks. I've installed audio gear in a few of them but was always on the front end...his included. If you have the carpentry skills building a ported box should be pretty easy even with the tranny hump to work around. The only concern I'd have is the narrow spot in the middle causing something goofy to happen with the tuning of the box. There are people on here that know way more than I do about that so hopefully they'll chime in. Big thing is the box must be PERFECTLY sealed up. You don't want any leaks at all.
EDIT: Looking at the box you linked to the narrow space over the tranny hump shouldn't cause any issues at all. I would build the ported box similar to the one you just bought, but go ahead and let the narrow part keep on going over instead of letting it drop down on the other side for simplicity sake IF you can get enough air space that way.